First, open up Start > All Programs, and search through the menu for the app you want to start at boot. Right-click on it and hit "Copy". This will copy the shortcut.Find the Startup folder in All Programs and right click on it. Hit "Open", and it'll open up in Windows Explorer.Right click anywhere inside that window and hit "Paste". Your desired program's shortcut should pop right up in the folder, and the next time you log into Windows, that program will automatically start up.