have one question though. How would I setup the "Custom User Interface" to run a cmd batch file?
Create the .bat file (let's call it "startup.bat")
Create a text file, paste these lines inside (edit it so that the path an application name are correct)
cd\
cd c:\Program files\internet
Start iexplorer.exe
de\
cd c:\Program files\google
Start Chrome.exe
Exit
Save and exit, then rename this file to "startup.bat" (check that file extensions are visible in your windows settings, it is important to delete the original .txt extension and replace it with .bat)
Now, go to "Custom User Interface" settings and choose the "startup.bat" file as the application you want to run (instead of 'mGalaxy.exe')
Note: to edit a .bat file (if you have to correct something), right-click the .bat file and select "Edit" (double-clicking it would run the commands inside!)